From a0f4c25a531bdc2619d150d825113aeec9c644b1 Mon Sep 17 00:00:00 2001 From: Fisch Date: Wed, 10 May 2023 00:13:29 +0200 Subject: [PATCH] calibrate ec --- include/ec.h | 9 +-- messung/20230509_Dauermessung.csv | 32 ++++++++++ messung/20230509_NaCl_manuell.csv | 49 +++++++++++++++ messung/20230509_NaCl_manuell.ods | Bin 0 -> 39952 bytes messung/20230509_NaCl_raw.csv | 36 +++++++++++ messung/20230509_NaCl_versuchsablauf.txt | 75 +++++++++++++++++++++++ messung/20230509_NaCl_vs_20230505.ods | Bin 0 -> 36752 bytes messung/approximate.py | 2 +- src/main.cpp | 4 +- 9 files changed, 200 insertions(+), 7 deletions(-) create mode 100644 messung/20230509_Dauermessung.csv create mode 100644 messung/20230509_NaCl_manuell.csv create mode 100644 messung/20230509_NaCl_manuell.ods create mode 100644 messung/20230509_NaCl_raw.csv create mode 100644 messung/20230509_NaCl_versuchsablauf.txt create mode 100644 messung/20230509_NaCl_vs_20230505.ods diff --git a/include/ec.h b/include/ec.h index 426b76c..ca6de35 100644 --- a/include/ec.h +++ b/include/ec.h @@ -29,7 +29,7 @@ uint16_t ec_calib_array_pos=0; uint16_t ec_array[EC_ARRAY_SIZE]; uint16_t ec_array_pos=EC_ARRAY_SIZE; unsigned long last_measurement_ec=0; -#define EC_MEASUREMENT_INTERVAL 60000 //complete filtered measurement every x ms +#define EC_MEASUREMENT_INTERVAL 30000 //complete filtered measurement every x ms //One filtered measurement takes EC_READ_INTERVAL*EC_ARRAY_SIZE*4 #define EC_READ_INTERVAL 10 //interval of reading adc value inside a measurement. one reading takes about 9-10ms @@ -57,10 +57,11 @@ float ec_reference_adc=6016.88; //adc reference value for the calibration resist //x^0*p[0] + ... + x^n*p[n] //float ec_calibration_polynom[]={691.5992624638029,-1.4015367296761692,0.0008513503472324141,-2.2140576823179093e-07,2.8962580780180067e-11,-1.8577565383307114e-15,4.7162479484903865e-20}; -//float ec_calibration_polynom[]={1033.928052655456,-3.8909104921922895,0.005627541436014758,-4.103988840997024e-06,1.7231981870816133e-09,-4.433707707721975e-13,7.203892111369395e-17,-7.406549810844244e-21,4.667420606439905e-25,-1.6439457516812463e-29,2.477292190335455e-34}; -float ec_calibration_polynom[]={212.6826331524675,-0.6043878865263305,0.000571551634082491,-1.827897106718841e-07,2.682337041246909e-11,-1.8368511021965982e-15,4.8269168538877025e-20}; +//float ec_calibration_polynom[]={1033.928052655456,-3.8909104921922895,0.005627541436014758,-4.103988840997024e-06,1.7231981870816133e-09,-4.433707707721975e-13,7.203892111369395e-17,-7.406549810844244e-21,4.667420606439905e-25,-1.6439457516812463e-29,2.477292190335455e-34}; //20220505 +float ec_calibration_polynom[]={-323.68589929771457,0.5836096440900665,-0.000279737392438965,5.98673062873e-08,-5.4460235093798435e-12,1.8535134644431135e-16}; //20230509 +//float ec_calibration_polynom[]={212.6826331524675,-0.6043878865263305,0.000571551634082491,-1.827897106718841e-07,2.682337041246909e-11,-1.8368511021965982e-15,4.8269168538877025e-20}; //20230509 manuell float ec_calibration_linearize_below_adc=6500; //use linear approximation below this adc value. 0=disable -float ec_calibration_linear_lowADC=750; //x0 +float ec_calibration_linear_lowADC=746; //x0 float ec_calibration_linear_lowEC=0; //y0 bool ec_measurementReady(); diff --git a/messung/20230509_Dauermessung.csv b/messung/20230509_Dauermessung.csv new file mode 100644 index 0000000..e5eb952 --- /dev/null +++ b/messung/20230509_Dauermessung.csv @@ -0,0 +1,32 @@ +time,tempReservoir,ECadcCalib,ECadc,ECadcAdjusted +101268,21.37,6017.88,8057.05,8055.72 +131325,21.44,6017.71,8031.89,8030.79 +161382,21.49,6017.91,8021.16,8019.78 +191439,21.54,6017.82,8007.08,8005.83 +221496,21.59,6017.95,7988.33,7986.92 +251553,21.63,6018.17,7974.48,7972.76 +281610,21.69,6018.26,7966.37,7964.54 +311667,21.75,6018.71,7956.08,7953.66 +341724,21.80,6018.76,7946.59,7944.11 +371781,21.84,6018.63,7940.63,7938.31 +401838,21.88,6018.53,7938.66,7936.48 +431895,21.94,6018.41,7951.11,7949.08 +461952,22.00,6018.60,7933.68,7931.41 +492009,22.01,6018.60,7924.54,7922.27 +522066,22.06,6018.66,7916.94,7914.60 +552123,22.12,6018.75,7911.43,7908.97 +582180,22.15,6018.97,7906.98,7904.23 +612237,22.19,6019.16,7904.89,7901.90 +642294,22.25,6018.83,7899.79,7897.24 +672351,22.27,6018.82,7898.05,7895.50 +702408,22.31,6018.77,7896.98,7894.51 +732465,22.37,6018.59,7890.25,7888.01 +762522,22.38,6018.69,7884.41,7882.04 +792579,22.44,6018.36,7880.67,7878.73 +822636,22.45,6018.04,7875.55,7874.03 +852693,22.50,6018.09,7872.04,7870.46 +882750,22.55,6018.07,7868.66,7867.10 +912807,22.56,6018.48,7865.01,7862.92 +942864,22.62,6018.35,7862.13,7860.21 +972921,22.63,6018.74,7857.67,7855.24 +1002978,22.69,6018.77,7858.07,7855.60 diff --git a/messung/20230509_NaCl_manuell.csv b/messung/20230509_NaCl_manuell.csv new file mode 100644 index 0000000..220b2e1 --- /dev/null +++ b/messung/20230509_NaCl_manuell.csv @@ -0,0 +1,49 @@ +ecMeasured,time,tempReservoir,ECadcCalib,ECadc,ECadcAdjusted +0,488810,25,6018.5,749.49,749.29 +0,500924,25,6018.5,749.85,749.65 +0,512968,25,6018.5,750.33,750.13 +470,607166,25,6018.38,6631.48,6629.84 +475,618283,25,6018.38,6632.4,6630.75 +480,630263,25,6018.38,6657.02,6655.37 +960,728530,25,6018.48,9028.83,9026.44 +965,739728,25,6018.48,9038.25,9035.85 +970,751586,25,6018.48,9085.94,9083.53 +1290,845876,25,6018.53,9975.25,9972.51 +1300,857889,25,6018.53,9956.18,9953.44 +1310,869129,25,6018.53,10024.26,10021.51 +3070,979125,25,6019,12369.85,12365.49 +3070,991238,25,6019,12391.81,12387.44 +3070,1003282,25,6019,12429.84,12425.47 +3620,1065510,25,6018.74,12577.39,12573.5 +3620,1079543,25,6018.86,12796.35,12792.14 +3620,1091656,25,6018.86,12823.02,12818.81 +30,1184837,25,6019.05,928.33,928 +30,1196950,25,6019.05,928.99,928.66 +30,1208340,25,6019.05,923.8,923.46 +380,1309239,25,6019.18,5713.99,5711.81 +380,1321252,25,6019.18,5718.64,5716.45 +380,1333296,25,6019.18,5738.1,5735.91 +710,1405519,25,6018.48,7862.59,7860.49 +710,1417563,25,6018.48,7861.14,7859.04 +710,1429607,25,6018.48,7859.18,7857.09 +1460,1488823,25,6018.43,10252.78,10250.14 +1460,1500836,25,6018.43,10266.79,10264.14 +1460,1511972,25,6018.43,10278.46,10275.82 +1960,1579122,25,6019.31,11072.54,11068.06 +1960,1596158,25,6019.48,11143.74,11138.92 +1960,1608171,25,6019.48,11162.37,11157.55 +2510,1661293,25,6019.38,11800.73,11795.82 +2510,1673306,25,6019.38,11757.97,11753.08 +2510,1684573,25,6019.38,11810.64,11805.73 +2840,1734501,25,6019.07,12125.58,12121.17 +2840,1746521,25,6019.07,12137.02,12132.61 +2840,1758704,25,6019.07,12165.2,12160.77 +3550,1821882,25,6018.94,12486.45,12482.18 +3550,1834006,25,6018.94,12587.85,12583.54 +3550,1845173,25,6018.94,12597,12592.7 +4220,1916439,25,6018.58,12688.82,12685.24 +4220,1928281,25,6018.58,12911.29,12907.65 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a/src/main.cpp b/src/main.cpp index 37f6e9d..429bb32 100644 --- a/src/main.cpp +++ b/src/main.cpp @@ -1,6 +1,6 @@ #include -bool debug=false; //print Serial information +bool debug=true; //print Serial information #include "helpfunctions.h" #include "ADS1X15.h" @@ -127,7 +127,7 @@ void loop() { Serial.println(); } - if (loopmillis>last_check+2000 && 1==2) { //check values + if (loopmillis>last_check+2000) { //check values last_check=loopmillis;